What I don't understand is how the extra O2 can make one more susceptible to the hit, any more than air can.
Surely the higher concentration of O2 in the bloodstream would mean that a hit would take longer to happen.
The issue here is that higher pressure O2 in the blood, can/will become toxic at some point--and that 32 % Nitrox would be more dangerous than air for this specific O2 toxicity issue.
The OP also mentions that she may have been less alert to an OOA or LOA due to CO2.
High CO2 can make the effects of nitrogen narcosis more accute, so more narc can mean less awareness of important issues like how much gas you have left, or how hard you are swimming.
If CO2 comes on the first thing you would do is to check your air!
Not necessarily, it could just mean harder breathing and more narcosis, and then less checking of critical issues....But often, it would mean some level of anxiety increase , more stress. The only good solution to fix this fast, is to ascend --even up to 30 feet or less, where you can rid yourself better of CO2.
Also, CO2 would begin after, as you rightly said, some exertion that would lead to rapid breathing.
But this rapid breathing is shallow, hence the CO2 buildup, and as such would not make you consume much more than if you were breathing normally. Remember - rapid but shallow breaths. Lower volume breathing that is.
High CO2 on a dive can easily come with rapid deep breathing...if the person is at all athletic, this would be what you would expect. And an athlete with good cardio will rid themselves of CO2 far better than their sedentary evil twin would, at any given depth....
Anyway, to state my understanding of it - and why I posted this inquiry - I believe that you are no more at risk from CO2 using Nitrox than you are using air.
Wrong. The issue here is depth...a diver getting to the limit of where a Nitrox mix is safe ( due to ox tox). High CO2 levels will cause the oxygen toxicity to occur at lower PP of O2 than normal.....and air has much lower PP of O2 for this deep dive than does 32% Nitrox...
But! Using Nitrox ( at the appropriate depth for the mix of course) would be a safer option, would render you less likely to be narced, and would make you MORE alert where OOA and LOA is concerned.
You should not expect Nitrox to reduce narcosis significantly, so no , I would not expect it to help with the OOA or LOA problems....you use Nitrox so that you end up having less nitrogen go into solution in your blood, during a dive ( because it has LESS nitrogen in it than air does--oxygen makes up for the volume of nitrogen that is absent--but too much oxygen gets toxic at depth, so Nitrox is not the big panacea for deeper diving....). And the amount of nitrogen is still high enough to cause plenty of narcosis...the way around this is to pump helium into the mix, drastically reducing the amount of nitrogen left for narcosis effects--and still keeping oxygen levels optimal for planned depth. For the Hole in the wall, we have a mix called triox, or hyperoxic trimix, that allows you to dive it like air or nitrox ( no gas changes needed), and it will provide you with an equivalent narcotic experience on a 150 foot deep dive, to an air or nitrox dive of perhaps 50 feet deep. Most divers who try this mix, and who thought they were sharp at 140 feet down, are amazed at how much more they experienced when diving the triox mix....!