If I remember correctly the Shearwater Perdix used to default to the highest O2 mix at the beginning of the dive until an update (probably because it was selecting the best gas …) which was annoying as you had to revert to your back gas in your selection.
You need to enter the gas mixes you have on you before the div, and during the dive, you only switches between the gas mixes to indicate what you are currently breathing.
I had buddies who forgot to set up the correct mix, so I think it’s a valid concern. I also have met people who didn’t understand that you need to deactivate the gas mixes you don’t carry prior to the dive, which is a bit worrying for people who dabble in light deco.
To answer your question, the AI computer only display the pressure of the tanks, you still need to enter in the computer the gas composition before the dive: the AI sensor is only a pressure sensor. It cannot analyse the gas itself.
Edit: checked if the perdix manual warns the user about making active a gas you don’t carry:
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