An obvious source of ignition in my mind would be static sparks from nylon-based under garments.
Not enough heat. 100% sure of that. A discharge of static electricity contains far too little energy to generate the heat required to ignite an undergarment. What happens in a static discharge is that a flow of electrons happens from A to B, usually using the human body as a sort of "ground" or "capacitor", therefore causing an electrostatic discharge with a measurable voltage that can be quite high but with a current of almost zero. The discharge also takes place very fast so the amount of energy generated is normally expressed in milijoules. The reason you feel it so well is that our nervous systems also work on these levels of energy, so it can feel worse than it really is. However, in terms of "heat", static electricity creates very little heat.
To put this another way, you can see voltage as how
fast the electrons are moving and current as how
many electrons are moving.
To use an an analogy, think of a garden hose. Voltage is how fast the water comes out of the hose and current is the volume of water that comes out of the hose. If both are high then the stream of water is powerful, maybe even powerful enough to cut metal. If the water comes out very fast but it's only a tiny little stream a few molecules wide then you might have to concentrate to even feel it.
That second thing is static electricity.
So in order to boil a liter of water with static electricity, or to start an undergarment on fire, you would need a sustained static discharge of a HUGE amount of time (I'm going to spare you the math here but let's just call it a HUGE amount of time) to create enough heat for our scenario.
R..