Your spit is filled with nasty bacteria and you absolutely aren't immune to them (your immune system can respond, and you usually don't get sick, but you definitely could get sick). You don't get sick all of the time because you swallow the bacteria and they end up in your stomach and get passed out of your intestines. Your digestive system is equivalent to the outside of your body. Your intestines actually have a very strong immune response. Your eyes have very little immune system protection, just antibodies and lots of tears to wash bacteria out.
Regardless of this, your body is pretty good at protecting itself, unsterilized water (which is filled with critters) is constantly getting in your eyes. While I am sure you could get an infection from your own spit (kids rub their eyes all the time and get eye infections) it just doesn't seem to happen very often to be a serious concern.
I use SeaVision Defog that came with my goggles. It comes in a spray bottle and works really well.