rrh once bubbled...
Go back to scuba 101 and Archimedes principle. Buoyancy is about displacement, not just weight. (Even my brother Jar Heads know this.)
A tanks buoyancy shift is not JUST about the gas, its about the container material, external size and internal volume. Remove or add, any equal amount of the same gas from or to dissimilar containers and there is a difference. For example, I have 38cf balloon and a 38cf cylinder full of He. I will vent 19cf of He from both
Seriously, reread Archimedes principle.
Note in your two examples the displacements changed, that's the key.
rrh started off so well and then took a turn into left field. He's (she's?) correct, it's all about Archimedes principle. So it's about just two things, weight and displacement. Absolutely nothing else, not materials and not internal volume.
As a cylinder is filled, we can assume it's external volume (displacement) does not change. It changes a little, but you need sensitive equipment (read: a hydrostatic tester's burette) to measure the change. So it's all about weight. Air weighs about 1 pound for every 13 cf. So for every 13 cf of air you stuff into a cylinder, its buoyancy decreases by 1 pound. So as an AL80 goes from full to empty, it's buoyancy "swings" 80/13 = 6 pounds. An HP steel 80 swings by 80/13 = 6 pounds. A hypothetical wood cylinder that held 80 cf or air would swing 80/13 = 6 pounds. A zillion ton nuclear submarine, if you vent 80 cf of air will swing 80/13 = 6 pounds.
This is because the displacement of a cylinder does not change from full to empty. So only it's weight, which changes at 1 pound for every 13 cf of air in it, has any effect on buoyancy
Now, what DOES change from steel to AL is the ENDPOINTS of this swing, and this IS due to the material. Taking some round numbers, an AL80 swings approximately from -3 to +3 pounds. A HP80 goes from about -9 to -3, a "neutral" 80 (misnamed for marketing reasons) goes from about -6 to 0.
So this is why you can typically drop weight if you move from an AL80. If for example you dive with 10 pounds with an AL80 and you switched to an HP80, the AL80 was -3 when full, the HP80 is -9 when full, so the delta is 6 pounds, so you could reduce your carried weight by 6 pounds, in other words drop your weight belt to 4 pounds. If you went from a AL80 to a "Neutral" 80, you could drop three pounds.
THIS is why you can drop weight when you move from an AL80 to steels.
So just to make sure: NO CYLINDER REMAINS NEUTRAL THROUGHOUT THE DIVE. If anyone ever tells you a cylinder can, they should run, not walk to the Nobel prize committee because they've just discovered a violation of one of the basic laws of physics that govern our lives.
Roak
Ps. This is why Genesis was so hot in his reply, this myth crops up from time to time, perpetuated by dive shop monkeys and marketing types that named the "Neutral" 80 to sucker people into thinking that it's neutral throughout the dive. We wish it this misinformation would just go away.