I think you have a small misconception here. Let's say we're talking about a 5-minute compartment.
After 6 half-lives in any compartment, that compartment is >98% saturated. So, in a 5-minute compartment, after 30 minutes that compartment is essentially saturated (presuming you have stayed at a constant depth the whole time).
If, at that point, you were to descend, your compartment would no longer be saturated, but it would equalize to ambient fairly quickly and you'd be back to saturated.
So, imagine that you are now at some depth and have been there for >30 minutes. That 5-minute compartment is saturated. You begin to ascend. No matter what speed you ascend, you are now supersaturated. Which means you are off-gassing. If you ascent to the surface without stopping (no matter how quickly or slowly), you will be supersaturated the whole way. Meaning, you will be at 100% saturation the whole way.
What the Buhlmann (ZHL-16B/C w/GF) algorithm says is that there is a supersaturation ratio during your ascent.
Let's say you were breathing air and you were at 100' for 30 minutes. 100' is 4 ATA. For ease of math, let's pretend air is 80% Nitrogen (instead of ~79%). After 30 minutes at 100', your 5-minute compartment is saturated, so your tissue tension of Nitrogen is 80% (the fraction of N2 in your inspired gas) of 4 ATA, or 3.2 ATA (approximately - this is a little bit simplified).
If you ascended instantaneously to 33', where the ambient pressure would be 2 ATA, you would have tissue tension of 3.2 ATA of Nitrogen and the inspired partial pressure of Nitrogen (i.e. the ppN2 in the gas you're breathing) would be 80% of 2, or 1.6 ATA.
That ratio of 3.2 : 1.6 is the over-pressurization gradient (in your 5-minute compartment). So, at that moment that you arrive at 33', that compartment has an over-pressurization gradient of 2.0. The Buhlmann algorithm is accompanied by a set of M-values. Those M-values are the Maximum over-pressurization gradient for each compartment. I don't know what the M-value is for a 5-minute compartment, so let's just say it is 4.0. Then, that would mean that, after your instantaneous ascent from 100' to 33', your OPG is 2.0 and the M-value is 4.0. So, your current gradient factor for that tissue compartment would be 50% - i.e. GF50. In other words, at that moment, your 5-minute compartment is 50% of the way to its M-value.
If you ascended at 30' per minute, instead of instantaneously, yes you would off-gas some from that compartment, so when you arrived at 33', your tissue tension of N2 would no longer be 3.2. The math to calculate what it would actually be is what is called the Schreiner Equation, which is part of any implementation of the Buhlmann algorithm.
Regardless, where your post was off is that as you ascend, your saturation level does not drop, ever.* That saturation level only decreases when you are descending (and even then, it only decreases if you descend fast enough to overcome the rate of on-gassing that is trying to keep you saturated).
When you are breathing air during the dive, that means you started with a body that was saturated on the surface. So, it has 0.8 ATA of Nitrogen in your tissues. As you breathe air and descend, the ambient pressure increases and the pressure of Nitrogen in the air you're breathing increases correspondingly. If you drop to 33', your body has 0.8 ATA of N2 and the air you're breathing has 1.6 ATA of N2. So, you are not saturated and you are on-gassing. If you stay there for 30 minutes, that compartment will be saturated. I.e. your tissues will have 1.6 ATA of N2 - the same as the air you're breathing. As soon as you start to ascend after that, you will go from being saturated to being supersaturated. Your body will have 1.6 ATA of N2 and the air you're breathing will be less than 1.6 ATA of N2. It will drop from 1.6 to 0.8 when you get back to the surface. Your body will gradually follow suit until it changes from supersaturation back to saturated with 0.8 ATA of N2.
* Note: That statement applies to if you are breathing air during your dive. Your level of saturation is always relative to the inspired gas (i.e. the gas you're breathing). So, any time you change breathing gases, your saturation level instantly changes up or down, depending on what you were breathing, for how long, your dive profile up to that point, and what you changed to.
I think we agree and it is poor wording on my part. my point that some of the comments sounded like they did consider that off gassing was going on during the ascent. My thing about no longer being saturated was (my fault) in relation to the deep depth prior to ascending and not the current depth where you will be saturated like you say. OR a slow enough ascent and you will not have tissues at the deep level when you get to say 50 ft from 100 ft. both factors are changing the ambient and the tissue pressure that the difference is measured with. Decreasing the depth increases the ratio while off gassing is reducing the ratio. I really think we are on the same page if only I could word it better.