Midthere:
I am wondering the process of becoming a Rebreather diver from scratch...
If you want to safely go much deeper than 120 feet with a rebreather, you would need to get trimix rebreather certified.
From scratch, does this mean you do not yet have open water scuba certification?
There are a few ways to move from scratch to Closed Circuit "technical" rebreather diver. Assuming you get certified the most common way via PADI as an open water and enriched air diver, you would need to still get advanced nitrox certification from another organization like IANTD or gain equivalent experience to do the gas changes required in technical rebreather. PADI also offers a rather extensive tech deep diver course which consists of a minimum of 12 dives and does a lot of deco and gas-change skill building. The latter would be overkill if you wanted to go to rebreather as soon as possible but not if you plan to dive a closed circuit rebreather in a technical capacity. IANTD's Advanced EANx Diver course combined with their Technical Diver course would be roughly equivalent to Padi's Tech Deep Diver course. IANTD Technical diver course requires a minimum of 100 logged dives, 1/3 of which need to have been deeper than 90 feet.
Though there are several ways to get there including PADI, TDI and other organizations open circuit training, for simplicity lets consider the IANTD way. An advantage to this compared to PADI is that an IANTD instructor may be more familiar with technical diving and rebreathers than the typical PADI instructor, and can guide you in a more direct manner. This is certainly not always the case, though.
Open Water Scuba certification: a few (part-time) weeks, $300-500.
Enriched Air Diver: a dive weekend plus academic time, $150-$300
IANTD Deep Diver, a dive weekend plus academic time , $150-300
Advanced Enriched Air Diver: one or more weekends plus academics, minimum 120 minutes underwater $300-500
IANTD CCR diver: 7-10 solid days, $1000 - $1500
IANTD Normoxic Trimix CCR Diver: one long dive weekend plus academics, $800 - $1000
IANTD Trimix CCR Diver: one long dive weekend plus academics, $800 - $1000
By the time you get to your Normoxic Trimix CCR Course, you need to have a minimum of 200 logged dives. Unless you are independently wealthy and can dedicate your time to diving, or you dive for a living, it will invariably take more than a year (as it should!) to become a full technical rebreather diver. Add that to the cost of a closed circuit rebreather and related equipment ($4,000 - $25,000), and you certainly have come a LONG ways in time, money and mindset from free diving!
Hope this helps.