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Well 100% isnt part of the class you referenced. And even if it was, you can do a max 10 mins of deco 3 times over on 2000psi of O2. Plus your question says that 3000psi is "overfilled" which is not the case either.pointless... this post was about 100% O2 in a cylinder , not PADI standards.
So what were you worried about at this point in your diving career? Just fill them to 2000psi if you are stressed about the (tiny) added risk of having the O2 boosted to 3K