If you're going to go for small doubles, I agree that 72s are the way to go. They're cheap and they'll be way more versatile than smaller doubles. You probably would do best to get a standard backplate; the freedom plate (at least mine) is not good for double tanks. A cheap AL plate will be very easy to find. You'll also need a bigger wing, (I almost typed 'wang' by mistake, hehe) unless your single tank wing is already way too big.
You're not really simplifying anything, though, over a single tank with a slung pony. Maybe consider a bigger bailout bottle, like a 30 or 40, which then still gives you true redundancy. The idea of trading a small pony for an even smaller one is stupid; it does nothing except make the bottle less useful. You still have an extra bottle with an extra regulator, it's not any less complicated or noticeably cumbersome. It just means you're carrying something that's not useful except in very specific hypothetical situations.
Regarding the training discussion, it is absolutely true that if you are diving solo in more challenging environments that are making you want redundant air, that's an indication that you have seriously increased the riskiness of your diving. Just getting the redundant air does not make that diving any less risky; many, many dive accident victims are found with plenty of air. So consider all the other aspects; navigation, entanglement, sudden illness, etc....and consider getting trained in solo diving by an excellent instructor. Everyone has his/her own risk tolerance, but I believe that many people fool themselves thinking that carrying redundant air takes all the risk out of solo diving. I'm not accusing you personally of that, I just think it does frequently happen.