That's easy... it's a rubbish deco gas!
To expand, it's great as a first deco gas which you can get on to at 21m/70', or even a bit deeper if you're in a mess (bailing out). However, half of all your deco will be at 6m/20', and at that depth the PPO2 of 50% is (mix x depth) is 0.8 which is lousy (half of what you're breathing is nitrogen which you're trying to off gas).
At 6m, or 1.6ATA, the Rolls Royce is 100% O2 meaning the nitrogen's nowhere to hide except floating upwards. This has its drawbacks (it's a very hot gas so CNS, OTUs, although this can be mitigated if you can finish deco shallower than 6m). 80% at 1.6ATA is a PPO2 of (1.6 x 0.8) is 1.28, which is enough to quickly get rid of the excess N2, but not enough to rack up the CNS and OTUs.
(Recently been though these discussions regarding bailout gasses when doing a deep bailout -- 50% is fine and dandy except it is too slow to deco. Even 60% is significantly better. Of course the best is to have two deco bailouts, 50% plus 80%/100%, but that's three cylinders worth with the bottom gas)