Hit it on the head. DOT4 brake fluid is 100% silcone.
From one of many hits: SynLube DOT 5.1 Brake Fluid
Ummm, No...
DOT 4 is not silicone. It is often a high performance synthetic that is compatible with DOT 3.
DOT 5 is silicone and is not compatible with other brake fluids.
Just going by the website - it says it's DOT 4 is 100% silicone.
Edit - but a whole lot more websites say you're right, that it is the DOT 5 that is silicone.
My bad. Thanks for the correction. Shame on me for hitting just the first one.