pipedope:
Many paints are heat cured and the heat will damage an AL tank resulting in an explosions at the next filling.
Paints that need no heat can be used but they are not so durable and may not be worth the trouble.
Having spent 10 years in industrial finishing, I can tell you with great certainty that there are MANY ways that you can paint a tank that does not require heat (at least nothing over 70 degrees F). Many of them however, do require spray equipment. Some methods don't require spray application but the obvious draw back would be aesthetics. In addition, the material cost would in most cases outweigh the cost of a new tank. However, if you have several tanks, it
might make sense.
A good, basic system for aluminum would be:
1) Thoroughly clean the bare aluminum surface (there are several ways to do this)
2) Apply a coat of industrial vinyl wash primer at < 1 mil dry.
3) Apply a coat of recoatable epoxy primer or sandable urethane primer
4) Apply 2 coats of Sherwin Williams Polane HS Polyurethane.
The above system can be used for steel just by omitting step 2 (you can do step if you like but it's not required for steel).
Follow the mixing procedures, application conditions and dry times and you'll be fine.
All of the above is a 10,000 ft view of "How to paint a tank". Feel free to PM me with specific questions or product recomendations.