As Capt. Scotty said, Hall Watts former owner of Forty Fathom Grotto in Ocala, FL set some world records back in the day diving on just air. Here's a copy/paste from the PSIA website.
"Founded in 1962 by a legend such as Hall Watts, the PSAI - Professional Scuba Association International - is based on the personal history, the desire to share his knowledge and the love for this sport of its founder.
He is the one who coined the famous sentence: Plan your dive - Dive your plan!
Hall, devoted to the development of diving technique for extended range diving, set in 1967 the Worlds Depth Record by diving on air to 119m and still holds the World's Record Deep Air Cave Dive with 125m of penetration. Pioneer of deep diving exploration, Hall is also the founder of the celebrated Forty Fanthom Scubapros team and has trained other seven Deep Record Divers."