Hey Seahorse,
MANY people are confused by all of the ways we measure tanks. One of the most common mistakes is to confuse the working pressure (3500 psi) with volume (80cf, 100cf, 120cf). All of the tanks have the same working pressure, but they have huge volume differences.
The cubic foot referred to is the gas at @ 70 degrees and at one atmosphere of pressure-NOT pressurized.
The 80cf tank has stuffed into it a quantity of room pressure gas that would measure 2'x4'x10'=80cf. Your tank is obviously NOT that big, so as they stuff this gas into it, the pressure rises... in fact once they get ALL of the 80cf of room pressure gas stuffed into this tank, it should read 3500 psi. With me so far?
The 100cf tank has 20 cubic feet (or 25%) MORE gas stuffed into it than the 80cf tank. The measurements of the room pressure gas used is 2'x5'x10'=100cf!
The 120cf tank has 40 cubic feet (or 50%) MORE gas than the 80cf tank stuffed into it. The measurements of the room pressure gas used could be visualized as 3'x4'x10'=100cf.
A good study for you would be to get a Chemistry book that deals with the ideal gas laws. It should also be in the advanced books of diving. In that you would learn that to stuff 120cf of room pressure gas into the 80cf tank the pressure would half to be 1.5 of what the 80cf was rated for. 1.5x3500psi=5250psi. In other words to get the SAME amount of air held by the 120cf tank into that 80cf tank you would have to fill it to 5250psi... THIS IS NOT RECCOMENDED!!! That is why the 80 cf tank is smaller than the 100cf tank which is also smaller than the the 120cf tank. I hope this sheds some light on the issues involved...