There surely are several effects. In the end, the "experiment" that was suggested above (static apnea time after pre-breathing O2) results in very significantly longer apnea times. Of couse in scuba diving we very often breath much higher ppO2 than on dry land, even when using air.
My basic point is that I doubt that in scuba diving these effects will result in the same dive lasting X minutes (with X being a substantial number) longer when using nitrox. Because for many divers, habitual breathing patterns will surely supersede the "breathing only when the urge comes". So delaying that urge by a bit more will not have a large real-life effect. But purely as an experiment, I would well believe that on nitrox, breath hold times would be prolonged.
My basic point is that I doubt that in scuba diving these effects will result in the same dive lasting X minutes (with X being a substantial number) longer when using nitrox. Because for many divers, habitual breathing patterns will surely supersede the "breathing only when the urge comes". So delaying that urge by a bit more will not have a large real-life effect. But purely as an experiment, I would well believe that on nitrox, breath hold times would be prolonged.