From Bruce Wienke, Technical Diving in Depth, Reduced Gradient Bubble Model (RGBM) In Depth:
Helium NDLs are actually shorter than nitrogen for shallow exposures . . . Reasons for this stem from kinetic versus solubility properties of helium and nitrogen, and go away as exposures extend beyond 150 fsw, and times extend beyond 40 min or so.
Helium ingasses and outgasses 2.7 times faster than nitrogen, but nitrogen is 1.5 to 3.3 times more soluble in body aqueous and lipid tissue than helium. For short exposures (bounce and shallow), the faster diffusion rate of helium is more important in gas buildup than solubility, and shorter NDLs than nitrogen result. For long bottom times (deco and extended range), the lesser solubility of helium is a dominant factor in gas buildup, and helium outperforms nitrogen for staging. Thus, deep implies helium bottom and stage gas. Said another way, transient diving favors nitrogen while steady state diving favors helium as a breathing gas.
http://www.scubaboard.com/forums/ad...aining-recreational-trimix-5.html#post6603329
The greater diffusivity of Helium from a free phase bubble model perspective (i.e. RGBM) means possibly loading idiopathic bubble seeds/bubble nuclei and having a Boyle expansion pathology resulting in DCS upon ascent --even if you were diving trimix within air or nitrox NDL's. . .