45ppm at the surface taken to 150 meters and breathed at 15 atmospheres would have a PPCO 15 times as much = 670, approximately. It's the PPCO risk of diving that is so different.
It's more complicated than that and riskier since CO binds with the red cells in your blood, releasing much more slowly than PPO, so as the latter decreases, the toxicity of the former hits even harder.
Where is that? It's not listed in your profile, which you might want to add for discussions like this. I actually bought my last two on Ebay for my daughter & I to use on car & overnight trips since most hotel rooms don't have CO alarms and some don't even have fire alarms.
This First Alert is shipped to most of the world, $17 USD with free shipping within the US but you can check the cost to you under
details:
First Alert Smoke Detector and Carbon Monoxide Detector Alarm SCO5CN 696579340175 | eBay
You need at least one in your home, one on your boat, and one for travel, but extras for backup are a good idea. Shop Ebay until you find enough.
I know nothing about rebreathers so I will have to bow to those who do and will post here.