Just a bit of a follow up.
Went to another local shop, requested 32% without draining the fill dude was able to get me to 31.7%, and filled to 3,800psi so it should settle down to around 3,400-3,500 psi (steel tank). Hopefully they remain consistent for the next 19 fills on my nitrox card.
I will be giving the old shop a chance with one last tank on my nitrox card before I put them on my NFE list, we will see if they can get +/- 1%.
Bring a dozen donuts and you’ll get 32% next time.