First DIN (Deutsches Institut für Normung) was not established until 1975 so making a DIN valve standard at the beginnings of SCUBA would be unlikely. NADI (Normenausschuß der deutschen Industrie) established 1917 and its successor DNA (Deutscher Normenausschuß) in 1926 had standards for industrial gas connections, but I don't know how much, if any, crossover there was between thir standards during these periods considering the intervening unpleasantness between the countries.
Check out
http://www.scubaboard.com/forums/tanks-valves-bands/310337-din-valve-history.html for a pre DIN "DIN" valve which was probably a DNA spec.
As an aside for someone who wants to wade through it, you will probably find a DIN specification for a yoke valve which, at that point, it will also be a DIN valve.
The reason the yoke is the standard in the US is that it has, and still does, work quite well for it's intended purpose. Additionally it's almost sailor proof.
Bob
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