I second this entirely.@OTF, humans don't inexplicably tolerate higher PPO2s in dry chambers than they do in the water. Rather, the changes in allowable PPO2 are based upon probabilities and risk mitigation. 1.4, 1.6, & 1.9 ATA aren't hard limits. In other words, you don't seize as soon as you hit 1.61 ATA on deco, for example. The higher your PPO2 goes (and the longer you stay there), the more likely you are to have a seizure.
In the water, a reg (or loop) needs to be held in the diver's mouth with a seal adequate to prevent the aspiration of water. This requires the diver to be conscious, i.e. not having a seizure. Because the consequences of a seizure in this situation are dire, the "allowable" PPO2 is decreased in order to decrease the probability of having a seizure and subsequently drowning.
Hard hat divers can use a higher PPO2, because the diver is less likely to drown if he/she has a seizure (because their gas supply does not require them to be conscious in order to maintain it). In other words, you can tolerate the increased risk of a seizure if the consequences of having that seizure are less dire.
Chambers can use a still higher PPO2, because even if the person inside does seize, it's pretty tough to drown when there's no water around...
When I did my first OW course, in 1975, most of the training was done using the ARO, a pure-oxygen CC rebreather (currently yet in use by military corps such as Italian Comsubin and US Navy Seals).
In the diving manual there were two "safety curves", relating depth with max time.
One curve was for "professional/military" use, meaning a rebreather equipped with a full face mask, which protects the diver from drowning in case of seizure.
The other curve was for "sport/recreational" divers, referring to rebreathers equipped with a normal mouthpiece.
The first curve had a maximum depth of 18 meters, 10 minutes.
The second one, instead, had a max depth of 10 meters, 10 minutes.
As my certification is recreational, my card says max 10m with the ARO (and max 50m with the ARA, that is open-circuit air).