The Kraken
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I usually breathe a mix with a PPO2 of 0.21 during surface intervals to help off-gassing. Am I being too conservative?

the K
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I usually breathe a mix with a PPO2 of 0.21 during surface intervals to help off-gassing. Am I being too conservative?
I'm sure I'll get stomped on here, but here goes anyway . . . .
PPO's are "RECOMMENDED".
We seem to be in an era of "less is better".
If I recall correctly, when I took my nitrox course it was posited that a PPO of 1.6 was the level which was recommended that a diver not exceede because beyond that level the possibility of oxygen toxicity was more POSSIBLY likely to occur.
For some reason, the 1.6 PPO seems to be interpreted nowadays as the level at which O2 toxicity WILL occur if the diver exceeds it.
I agree with prudence, caution, safety and so forth, but there comes a time when being safe becomes being paranoid.
I can understand not diving beyond 1.5 or 1.4, but when we start getting to PPO's of 1.2, or 1.1, or 1.0???
What's next???
Let's not dive beyond 0.5, that way we'd be really safe.
I have no compunction about diving a PPO of 1.6, although I prefer, for safety's sake, 1.5 or 1.4.
But, in my opinion, going to such reduced percentages of O2 effectively negate the rudimentary reason for diving nitrox.
Just my opinion.
the K
They could have been certified ages ago. NOAA Nitrox I (32%) was chosen to hit its 1.6 MOD at 130 fsw to match up with the limits of rec/NDL diving. Since then the MOD limits have tightened up to 1.4 and with some agencies recommending no more than 1.2
What's frightening about Nitrox is the page of studies in my Rec Triox workbook . . . The variability between individuals and with the same individual on different days is enormous. It makes it quite difficult to propose a ppO2 above 1.0 that could be considered to be "safe". For a long time, 1.4 was felt to be pretty benign, but I know of two incidents where people seized on 1.4, and one died. It is extremely difficult to manage a seizing person underwater, and rarely successful even if the divers involved have extensive training. I don't want to risk it, myself.
There is a difference, too, in the motivations of recreational and technical divers. For a tech diver, reducing the ppO2 means doing more deco -- which in the majority of cases, is quite possible. Although hanging in cold water isn't fun, the people who do it are trained to do it, and the risk of more deco is substantially less than the risk of toxing. Most of the people I know who do staged decompression diving are very respectful of that risk.
But recreational divers have a motive to push ppO2s . . . more bottom time. Since they don't intend to go into deco (as a general rule) they are constrained by that pesky NDL. So it becomes attractive to use the hottest mix that will permit keeping ppO2s to whatever the diver has decided is safe FOR HIM. One hopes that's the agency's chosen standard, because the recreational diver is least likely to have a buddy who can recognize oxygen toxicity and manage a seizing diver to the surface.
By any definition I've seen, if it contains gases other than Nitrogen and Oxygen in more than trace amounts, it's not nitrox.
In any case, I get narced at 100 feet on air (at least in the conditions in which I usually dive), and 150 on 25/25 is like 100 on air. Personally, I'd rather a little more helium and a little less oxygen, since adding the former doesn't hurt (wallet aside) and subtracting the latter is a more conservative (tox).
To me, toxicity and narcosis are the biggest concerns from a gas selection standpoint. Deco is what you live with after addressing the primary considerations.
What's frightening about Nitrox is the page of studies in my Rec Triox workbook . . . The variability between individuals and with the same individual on different days is enormous. It makes it quite difficult to propose a ppO2 above 1.0 that could be considered to be "safe". For a long time, 1.4 was felt to be pretty benign, but I know of two incidents where people seized on 1.4, and one died. It is extremely difficult to manage a seizing person underwater, and rarely successful even if the divers involved have extensive training. I don't want to risk it, myself.