for me, w/ Pinnacle Evo2 (stock shoulder dump), I have no issues at all getting all the air out, I normally keep the valve all the way open and if I need to vent some just roll slightly to my right and air flows out easily. I really think that Pinnacle placed it just about perfectly, it very high on the shoulder somewhat towards the back, if it were farther forward it would be easy to get a hold of, but would be much harder to vent normally.
as for the idea of a back-up exhaust, I thinks that's a very bad idea. with 2 all you would have is 2 failure points that need to be cleaned, rebuilt, get caught up on things (wrist more so than shoulder). even with dry gloves on you already have a backup exhaust built into your suit, its called the neck seal. with a properly sized seal, just get upright and twist your neck or look straight down, air will find its way out pretty easily. if that doesn't work, grab hold of it and pull, so long as you don't create a huge gap, air will leave and really no water will get in.