Here's a link to the Catalina cylinders page-
SCUBA Cylinders
Bottom line- 19 is 2.1 pounds heavier and 4.7 inches longer than the 13. Diameter is the same.
Filled buoyancy is only 2/10s of a pound different and empty is 6/10s of a pound, no really meaningful difference.
The 19 is about a 45% increase in capacity over the 13.
The best way to answer your question is to figure out your air consumption (Preferably under stress) and look at the depths you will be diving and then figure out how much air you could need to extricate yourself from the problem or situation that caused you to run out of air, make an ascent at a safe speed and hopefully even toss in a safety stop.
And then toss all of that out the window when you figure out that if you have to donate it to someone else you have no idea what their air consumption is but that they will likely be pretty agitated by having run out of air and the bottom line is really that the more air you have the better!
For me the added length is not important- the two biggest changes between the cylinders is a 2.1 pound increase in the dry weight in order to get a 45% increase in capacity, I've always felt that 2 extra pounds was probably worth the extra margin of safety.
Good luck with your decision!