You guys are forgetting that cells have an established mV starting point, for most analyzers its 9-13 mV. You can't just start with "any" voltage reading and somehow play with the dial enough to get it to calibrate. Sure mathematically you could put a 1mV cell in there are turn up the potentiometer to the max and get it to read 0.21 and the cell wouldn't be capable of reading past 0.25 and that would be "dangerous". But the reality is that doesn't happen because while a 8mV in air cell could calibrate to 0.21 and read (perhaps) up to 0.95 once that cell falls to 5 or 6 mV in air its not going to read 100% at all. Instead of thinking your deco mix is off you suspect the cell, in part because you cranked up the potentiometer just to get it to read 0.21. By the time a cell won't read 0.32 or 0.36 its so far gone that you can't even get it close to 0.21 at the start, so even with a "one point" calibration you notice the issue. The reality is that OC divers aren't being killed by failed analyzers, its when they don't use an analyzer at all.
This would be an important point. Any tests showing the potentiometer range in the common o2 analyzers? I quite certainly can crank up a low cell in the few I've tested.