According to my tech instructor, there is a significant safety advantage in terms of fire with 80% when compared to 100%, especially when a tank is overfilled. .
I would like to see some documentation on this. The information I had, which I believe came from Vance Harlow's Oxygen Hacker's guide, is that in examining the Gus Grissom tragedy, NASA determined that anything over 50% had a reasonably similar chance of making things go bad.
We know what really happens but I was just stating the facts. That is why you have to have a booster to pump O2 at higher pressures.
100% is readily accessible. 80% is a headache to obtain.
This can be an important factor for people (like me) who frequently dive in places where we don't have access to shops who make these kinds of fills regularly. I have done many, many dives where any nitrox mix, up to including 100%, was created by partial pressure filling from whatever we had on hand from an industrial O2 bottle, with no booster within hundreds of miles. That means you can't create a full 3,000 PSI of O2 even if you are starting with a full O2 bottle for your fills. When making fills, you have to plan the order in which you fill tanks very carefully so that you will be able to make as many 100% O2 fills at reasonable volumes as you can before doing the 50s and other mixes. As your supply bottles dwindle down, it becomes very tempting to top off the 100% bottles with some air for the sake of volume.
First of all, I agree with the preference for 100% O2 for the reasons already stated by many. On the other hand, I have used 80%. When I got my advanced trimix training, we did all the training dives on 80%. It was not just my instructor's preference, it was clearly what most people on the boats we used were using. The fill shop we used had 80% banked. It was the popular choice, and I was not going to make an ass of myself insisting on using 100% and being the only one doing it. I am able to make ass of myself in too many other ways to add this topic to my repertoire.
I did not think it made all that much difference. We made the final switch at 30 feet instead of 20. Fine. I asked the others why they preferred 80%, and they never gave any of the reasons you hear about. They did not talk about holding stops in swells, and their buoyancy control holding stops was plenty good. I got the sense that it was just something they had always done. I gave my instructor a copy of the Bakers Dozen for his amusement. He had never seen it before. He frankly thought it was silly.
That was a few years ago. I still go to that part of the country and do deco dives each year. It seems to me that 100% O2 is more the norm now than it was then. Still, if I ended up diving with a group that wanted to do 80%, and I was joining them, I would just shrug and go with the flow.