captain
Contributor
Geez, after 3 pages of useful responses, nobody answered the original question, which was really quite simple. You will get ~ 25% more down time if nothing else changes by going to a HP100 because you are now have an extra 20 ft3 of air. If you could stay down for 30 minutes w/ an 80, you can now stay 37.5 minutes.
Double 100's will give you 2.5X more air than a single 80, but you can't really plan 2.5X more down time as you could be exceeding your NDL on a dive of that length and a different set of dive planning rules are needed.
John
You need to learn how to calculate your SAC, do it and get your own answer as to how much gas will be needed for a dive to a particular depth and time. It will also show if you are improving your air comsumption.