No, there is no reason not to use 63s for DIR diving! But they're good for longer, shallow dives, not for deep ones. The reason is actually pretty simple, and it's called "rock bottom", or "minimum gas". We always carry enough gas to get ourselves and a teammate up from the deepest point of the dive to the first gas switch (which may be the surface on a deep, non-decompression dive), making all appropriate stops. That amount of gas reserve starts to get substantial as you go deeper -- for example, it's 40 cu ft from 100 fsw. Since your gas consumption continues to increase as you go deeper, there comes a point where small tanks just don't give you much bottom time AND enough gas reserve. I'm fairly sure Kathy is interested in doubles for deep dives in Monterey, and 63s would quickly be inadequate for that.
But I would imagine that sets of small doubles would be great fun for shallower dives. Doubles just dive so much nicer than single tanks!