Could you expand on that aspect? Thanks.
The current models for computing deco stops are basically yet an evolution of the old approach of Haldane: a set of parallel and fully independent "first order circuits", usually called "compartments", each charactaresid by just two numbers: the emisaturation time and the max oversaturation ratio.
Even the more advanced Bulhmann 16-compartments model behaves substantially according to this basic approach.
After proper tuning of these two parameters for each of the 16 compartments, this model has shown to be able to plan diving profiles which are reasonally safe for the vast majority of recreational dives (which include deco stops, as already amply discussed, and usage of Nitrox).
But these recreational profiles do not include trimix or changing mixture along the dive.
Albeit this model has also been employed extensively also for diving with heliox and trimix and for accelerated deco with high-oxygen mixtures (after some re-tuning of coefficients), the phoenomena happening in our body in these conditions make the basic model quite far from reality.
In our body there is no "separation" between "compartments", we have instead a number of different tissues and organs which communicate each other. The components of the gas mixture migrate from here and there following complex diffusion and convection phoenomena.
These should be accounted for by means of a more complex equivalent circuit, with links between compartments.
These phoenomena are exacerbated when the gases are moving pushed by strong pressure gradients.
So, while for a normal dive in air, with deco also in air, the pressure gradients are small, resulting in negligible effects of this inter-compartment gas migration, when you speed up the deco forcing large pressure gradients thanks to breathing (almost) pure oxygen I think that the basic Haldane model becomes too distant from reality for being thrusted.
Said that, my knowledge is not deep enough for proposing a more realistic model suitable for accelerated deco. I see the problem, but I do not have a reliable solution.
So I did never shorten my deco stops even when an higher-percentage of oxygen was used during the last part of ascent and deco stops (a case which happened to me perhaps 4 or 5 times in over 1000 dives).
The benefit is usually just a few less minutes of deco, and I did never think that such "advantage" was worth the increased risk and the hassle of computing this deco reduction.