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If you have to overfill al80s by 750psi you are either starting with a crazy hot bank or going super fastit is, but if it's actually 130F when you stop filling, then it should cool back down to 3000. I usually set the regulator at 3500 if they're coming up from low pressure and they almost always settle out a hair under 3000, and yes the regulator is calibrated and accurate to within 1%
So 130*F (590 R) to 68F (528 R) would be 89% of the the pressure when hot. 528/590 = 0.89
@Jwoobs math of a ~10% drop is closer to my experience. My al80s are filled to 3300 and they cool down to 3000.
If I filled to 3750 they would cool to 3400-ish.