Wetvet,
As posted, your neckseal, is more a culprit than breathing air, but air is not helping. Simple things like a 'one notch too tight' neck seal will create a chain of events regarding the lack of O2/blood supply to your head, thereby triggering the body to increasing CO2 to force you to breathe harder. The vicious cycle just gets worse and worse even if you do absolutely nothing and just breathe and hover simply because of that ill fitting seal.
So, with that build-up generated as a by-product being produced faster than it's being metabolized, you're looking for ways to minimize it (in fact, your body needs a little CO2 in the system). It's also 120x more narcotic than N2. Narcotic potency is measured as inverse proportion to the square root of the molecular weight of the gas. Yes, it may be 5x heavier, but the effect is 120x more potent. Metabolism helps, but just recognize that somewhere between 5x-120x is the truth and that just plain sucks!
What do I do??
-Trim the seal and get a good fit that doesn't restrict blood flow to the head. OK, can't do that underwater.
-Slow down and move slowly. Reduce your effort.
-Breathe deeply and deliberately. Shallow breathing is common with CO2 buildup.
-Reduce N2. Add more O2 or He. RBC rigidity from N2 was already mentioned. Plus, N2 is heavy to breathe especially with a tight neck seal. Yes, O2 is narcotic as well, but it's also metabolized and the key ingredient that you're trying to get to your head! Unfortunately, there's no oxygen window benefit with Nitrox less than EAN50 at the recreational depths that your talking about. Plus, you don't want to open that window when you're working. However, EAN32 still gives you advantages over EAN36 or EAN40 (again no real O2 benefit) by giving you 1) the depth flexibility and 2) the benefit of added NDL time. Of course, the best choice is 30/30 for your dive. He is so much easier to breathe and its benefits already mentioned. Real benefits of He are physiologically noticeable with contents of 30% and greater. You've basically reduced your N2 content by half when compared with air. It is also the gas of choice for extended exposure (beyond NDL) at recreational depths.
You can conduct some simple tests: dive air, Nitrox 32, and 30/30 (of course after you get proper training) and swim at 90ft for 100 yards, complete the dive and record how you feel immediately after the dive, 1 hour, 2 - 3 hours, and then 4 -6 hours. Even with a tight seal, I don't think you'll run into problems with He. I've tried to work hard to increase CO2 at 100' with 30/30 to see if I could get that 'out of gas' feeling. Couldn't do it. Or trust those that have tried it, and start feeling good from now on out!
DIR is about taking every advantage possible before, during, and after the dive, and gas selection is one of many considerations...Do I dare say your equipment is another?
Hope that helps.
Sincerely,
H2