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I am going to assume since you did not mention it were talking about an axial, not radial or ER radial.
Sorry not to sound rude but your asking why you had a potential CO2 breakthrough when your telling everyone you planned a 65m 165 min dive in 12 degree water with 12/65 trimix and a scrubber that already had 130min on it???? Am I understating this correct?
Just a suggestion you might want to read through your JJ manual and check with your certified JJ instructor on what a safe scrubber duration is, especially when your diving in cold water. I doubt your instructor or the manual will suggest over running your scrubber by almost 2hr. and I would bet big money that the reason they tell you not to over run your scrubber is risk of a CO2 hit.
Also little off topic and not that it is any of my business as everyone is free to dive how they want but I think I might reflect on your diving style/diving mentality because having done tons and tons of 65m-70m dives with 45-60min bottom time 120min deco plan sounds very very aggressive especially is cold water. Personally a 65m 45min bottom time dive for me I would have a total run time of about 185min not 165min and that is diving a 50/75 GF. So to get to a 165min RT would be like diving a 50/90. If you never have issues great I'm all for getting out of the water faster but personally I would rather play things a little more conservative. Same goes for your scrubber durations. But like I said everyone is free to dive how they want just some of use are more conservative than others.
Yes you and your friends might get away with over diving your scrubber 20, 50, 200+ times but what about the 1 time when you don't get away with it. Same goes with diving super aggressively, yeah its nice to get out of the water quicker but remember decompression diving is not an exact science and everyone's body is different. Additionally when you start doing 3+ hour trimix decompression dives remember your tissue loading is extremely high and having some contingency scrubber run time for dives like this is something you might want to keep in the back of your mind when dive planning. What happens if you or your dive buddy starts to get join pain on ascent at your 12m stop and now you drop back down and add 60min of deco to your plan. This would now put you 3hr over your scrubber time that is twice the manufactures rating.
Like I said not trying to sound rude but just some things to think about the last thing we all want is to read another accident report. As another rebreather diver I am all for supporting others and trying to keep the sport safe and help it grow as an industry. For along time rebreathers had a bad reputation but with modern training standards and conservative manufacture recommendations and diving practices rebreathers are an extremely safe way to dive.