dumpsterDiver
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I might suggest that TSandM's experience is due to a small pressure differential between her lungs and her mouth/reg (assuming a perfectly horizontal posture, her reg will be higher than the mean of her lungs) which forces a subtly larger volume from her lungs upon exhalation (and a smaller volume into her lungs with inhalation) when on her back as opposed to on her front. This might make her less buoyant on her back.
As for being less buoyant feet-up vs. feet-down, I cannot rationalize this unless the act of inverting ones self drives one's BC slightly deeper, increasing compression.
Have fun diving!
I was just going to post the same suggestion. I myself never noticed this to occur, but it makes sense.