You appear to be correct, the D4i does not seem to have the ability to change to 50% RGBM from the normal 100%. You can only make sure that you are on personal adjustment 0. the least conservative. The computer runs regular Suunto RGBM, moderate on the 1st dive, often more conservative on repetitive dives due to penalties (SI, ascent rate, profile...)
Your Smart Com runs Buhlman ZHL-8 ADT, generally moderate to conservative. Make sure you are running at setting L0, least conservative.
Always run your computers at the nitrox percentage that you are using, none of this air stuff.
You obviously missed a deco stop on your Suunto on the dive you describe and went into violation gauge mode, or worse, no function. I have never dived a Suunto. You will have to monitor both computers, satisfy any deco obligation to avoid the lock out. Both of these computers are moderate to conservative, I would not worry too much about approaching NDL or satisfying short deco obligations. Of course, this brings up gas planning and making sure you have plenty of gas to complete your dive. As a divemaster/instructor, these things should be perfectly obvious to you.