I think the problem is a very old tradition that is in the midst of change. The tradition is that we dive with tanks filled with air, and the only tanks that get filled with nitrox are clearly marked as such. You don't put one in the other. That is simply no longer true. All of the tanks I own are O2 clean; not one of them has a nitrox sticker. That is true of almost everyone I know well.
I don't know how many milliions of basic OW dives are done throughout the world annually on air, without anyone giving a thought to analyzing their tanks. How many basic OW divers getting onto a dive boat for a 2-tank dive on air have analyzed those tanks to make sure that it is indeed air in those tanks? I would say the number has to be far less than 0.0001%. How many basic OW divers on basic OW dives have had an incident as a result of accidentally breathing a nitrox mixture instead? I would guess the number would be far less than that, and I would almost be willing to bet it is a flat zero. Why? It is not just that I thnik the operators have that system pretty well figured out. It is also because I think the margin for error in the MOD standards is so large that I wonder if it is even possible for a diver breathing a standard nitrox mix in an AL 80 in a dive to recreational limits to have an oxtox event. IT doesn't happen when you drop below the MOD by 5 feet for 15 seconds.
There is another reason. I was diving with a student a few days ago, and we took a lot of tanks from our dive shop with us. They were all air. The student asked if we should be analyzing the tanks to be sure, and I said that IN THIS CASE, I was not concerned with it. Why? Because I knew darned well the shop does not have the ability to blend nitrox. They don't have an O2 bottle on the premises, they don't have a transfill whip on the premises, and the only one who works for them who knows how to blend it is me. You might be surprised how many operators do not have enough demand for nitrox to make their own. The only thing they can possibly put in a tank is air.
The real problem comes with situations like the one in this thread. It comes when people have the capacity to put any mix in any tank, no matter what it looks like. I did not bother to check the air tanks in the situation above; if the situation were different, I certainly would check.