Aren't all VHF radios made to monitor ch 16 even if their preferred channel is another?
No. There's a features called "Digital Selective Calling" or DSC. I think every country uses it. In the US, all marine radios were required by law to support DSC as of 2009.
SOLAS is an international convention that also requires radios to support DSC. For Class A vessels (big ships, cruise ships etc) the vessels even have to serve as DSC/Emergency repeaters.
Information on SOLAS:
SOLAS Convention - Wikipedia Edit: everyone except Bolivia, Lebanan, and Sri Lanka are a party to the SOLAS convention.
So.. even if you're listening to channel 7 on your marine radio.. if someone uses the emergency mode to broadcast on channel 16, everyone within range will hear that broadcast. If there's a class A ship within range, then a whole lot of radios will hear your broadcast.
Here's info on DSC from wikipedia:
Digital selective calling - Wikipedia
Here's more detailed info from the US department of homeboy security:
Digital Selective Calling
Here's info from the US FCC on Marine radio:
Ship Radio Stations
Note that channel 16 is not the only reserved marine channel. For example, channel 6 is "INTERSHIP SAFETY - Use this channel for ship-to-ship safety messages and for search and rescue messages to ships and aircraft of the Coast Guard."
Obviously the FCC or DHS are not the world police, but I believe most countries take this stuff very seriously.
I was unable to find when DSC was created. My money would be in the 70's or 80's. A listening watch aboard GMDSS-equipped ships on 2182 kHz ended on February 1, 1999. I'm sure it was around a LONG time before it was decided that having a human simply listening to channel 16 was no longer going to be a thing.
Now, boats might be using radios other than marine radios in coz (I doubt it but you never know I guess). If they're using a marine radio made since 2009, they definitely support DSC. If they're using a radio made since 1999 it's very likely it supports DSC. If they're using a radio older than that, they should mail it off to the Smithsonian.