I think the "spark" reference refers to a higher potential for entrained ferrous particles from elsewhere in the copmpressor/fill station/tank system to spark if they impact the comparatively rough Ti surface. The other caution involves the oxides that form on a Ti surface that are for all intents and purposes impossible to remove making proper O2 cleaning much more difficult.
...and pressure and velocity that generates friction/heat in the first stage. This info comes from a very well informed source.
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