Watch your guages and come up with enough air. Practice good buddy communication. Spare air might not hurt, but it won't help either. Know your air consumption, dive conditions, your stress levels, and your ability to task load. Spare air can take time to grab that is too precious for a CESA, especially if you are not good at task loading and are stressed.
If you need the extra air, dive doubles, or a 45 as extra. This procedure is only necessary for diving beyond recreational diving.
If you want more time underwater, get fit, breath calmly and slowly, and consider Nitrox mixes. On a recreational dive, I recommend ascending with 500 psi and turning the dive at 1000 psi. Get comfortable with those numbers before you push the limits, so you can learn your limits and capabilities safely.