Every dive, every flight.
What are you using to check your tanks for CO2, and why do you suspect a possibility of a presence of that gas fraction?
IF your arugment is your process for OC diving is infallable, and flawless, come up with one really good reason you should be diving a rebreather? With enough planning/equipment OC can be faster through deco, and another layer of felt gives you the warmth under a dry suit.
You've suitably convinced me you do not accept all the risks with diving a CCR, and I'm trying to figure out why you're doing it.
I happen to have a spare CO2 Sensor (I removed it from the rebreather), so I use it to check the tanks for CO2.
A properly designed filling station, if functioning properly, would convert by filtration the CO (if any is produced) to CO2. So, in addition to the 0.03% - 0.05% normally in ambient air, you could find a not insignificant presence of CO2 in the tank (which means you have a big problem with your compressor).
Interestingly enough, if that were to happen, on OC you could die, but not on rebreather because the CO2 absorbent would remove the excess CO2 (if it is not too much of course).
I have explained why I dive rebreather in a prior post.
For certain cave dives, it is logistically preferable to use a rebreather. I would need 10 Sherpas to carry up and down the equipment for me in and out of the cave if I were to do the same dive on OC.
Other than for long cave dives over a series of consecutive days, I do not use a rebreather.
Before I fully understood the true risks inherent in rebreather diving, I used to use the rebreather every dive. Now, I avoid it like the pest whenever practicable.
It is a useful tool though under some circumstances where the benefits outweigh the risks of using a rebreather.