I believe he is referring to an old and very much debunked theory that when PPO2 is highest, the biological processes involving oxygen being converted to CO2 create an "oxygen vacancy" that essentially creates more room for nitrogen to leave the tissues and thus speed up decompression. This theory is not talking about the simple gradient difference created by the relative PPO2s of nitrogen.
This theory was first embraced by people in the DIR community, led by George Irvine. The deco processes for GUE and UTD used to accommodate this belief by extending the time for the deepest stops after a gas switch. Thus, in contrast to all other decompression plans, their 70 foot stop with the switch to 50% and the 60 foot stop would be longer than the 50 and 40 foot stops. This created what was called the "S-Curve" profile that was a key aspect of Ratio Deco.
From the start, people pointed out that it violated Dalton's Law. When I read the study, I was stunned--the conclusion leaps out in one paragraph with nothing preceding it that I could see that would lead to it. When I was a UTD diver and was required to follow that profile, I argued against it. Mark Powell flat out said it was wrong in his first edition of Deco for Divers. Eventually, GUE also decided that the theory was wrong, but it originally kept the S-curve in its teaching because it had apparently been working for them. (I still have JJ's explanation of that.) It eventually moved to a linear ascent in that part of the ascent profile. At the time I left UTD, Andrew was also saying that the theory might not be correct, but he was still using the S-Curve at the time of the recent Spisni study.
For many people, the theory was close to sacred for many years. I am surprised when I run into people who still believe in it, but they do exist.