...for contributing to this discussion ( my question's genesis is a point made in a "Rescue" thread over in the Advanced Diving section ).
Well, I'm a little out of my depth here as a snotologist, but I'll give it a shot... you will get better answers from the real docs here!

Now, what about the time frame? Any suggestions as to how long one might remain in spasm after loss of conciousness?
I doubt that there is any human data to answer that question, but remember it is not the loss of consciousness but the progression towards a hypoxic brain death that you seem to be tracking. Unconscious patients can and do have prolonged laryngospasm, but eventually progressive hypoxia and hypercapnia (elevated carbon dioxide) would override the airway protective reflex that is (when exaggerated) larygospasm.
Further; I've queried several doctors on the subject of cardiac sustainability after cessation of respiration, & have received a variety of estimates. Would anyone care to speak to that issue?
Temperature has a lot to do with this.... there are a number of case studies of young drowning victims in cold water for up to around 30 minutes who are successfully resuscitated. As they say in the ERs of the great white north, "you are not dead until you are warm and dead". In general, though, successful resuscitation is rare after more than 5 minutes or so of apnea.
Lastly, how imperative is the "chin-up" posture for the patient's head when ascending during a rescue of an unresponsive diver? I have read one opinion where the author opined that pulmonary air will escape regardless of the patient's head position because of Boyle's Law, though this seems to run contrary to conventional wisdom as I understand it.
That actually has more to do with clearing the obstruction to the airway caused by the tongue. When you are resuscitating someone (above water), you do a head tilt maneuver to move the base of the tongue away from the back of the throat, to make respiration easier (spontaneous or by resuscitation). So this is more of an issue once you hit the surface. As far as air escaping from the chest during ascent, it shouldn't matter either way, since the expanding gas will push its way out one way or the other, thanks to Boyle...