I haven't found the time to do bibliographic research yet.
This forum is fun but there can't be much time to dedicate to it.
However, it is false to think that gases mix homogeneously. The speed of the molecules will tend to make stratification faster towards the bottom.
Just think of the disaster (not related with diving):
en.wikipedia.org
If there had been no stratification, no one would have died ...
This is just an example. There are other testimonies in the history of diving, for example in the first full face masks the CO2 collected at the bottom, where the mouth is. To avoid intoxication many (I think everyone in the Royal Navy) mounted a mouthpiece inside the face mask, to avoid breathing in stale air.
Also here there is an aggravating factor: an expanding gas in the central part of the lungs that exerts
higher pressure on the walls where the CO2 is forming and will tend to create a "gas wall", even if not perfect.
I note that just on this forum you can read about divers who after a CESA of 25 feet [that is ~8m] at the surface had lungs that were burning: CO2, without a doubt.
What happens if it is not 8m but 40m and the diver does not have the skills and self-control of a freediver?
@CG43 you say that it is possible to make an ascent from high depths...
I have never questioned it, but you talk about 1 minute 2 minutes of breathhold... But look, a normal diver does not hold his/her breath for more than 30 seconds (like my wife).
So with good reason and
very responsibly PADI does not suggest a CESA of more than 9 meters, because most divers are NOT capable of doing much more without getting into trouble.
And you can't give a recipe that not everyone is capable of following.
Doing so would be deceptive, it only serves to provide an illusion of safety, and presumably a death sentence for the unaware inexperienced diver.
I read that George Bond made ascents from 100 meters (but from a submarine or with scuba?, we know very well that they are very different things. And then 100m? or 100ft?). But George Bond, the "papa topside" in SEALAB I project, was an old diver, a true pioneer, with the nose-clip (it is even documented that he was a big supporter of it) and all the rest. And obviously he also had a freediver training.
There is a mention to leave the weights (but in the true CESA you have not to do it, really). A modern diver often dives with 10kg of weights. Without a functioning BCD I see it as hard for a diver without freediver training to get out without damage, I see it as hard to be able to control the descent.
And let's leave aside the rope [I didn't have it in the sea trial] and the truth is that it is difficult to have any kind of similar help when disaster strikes...
Instead an old diver, without a BCD, rarely used more than 2 or 3kg, from what I read and with a freediver training he could be able to keep calm, tolerate CO2, and swim actively at the speed required at the given depth.
Let's see if I can find some interesting documentation and not anecdotes.
But in the meantime I just read, on:
The Controlled Emergency Swimming Ascent (CESA) shouldn't be used except in emergencies. Learn more about what it is and when to use it.
www.scuba.com
"Some experienced divers have experienced success with this skill at depths beyond 30 feet, but as a general rule (and following PADI guidelines) this skill should not be attempted from deeper than 30 feet."
He is saying that a normal diver is not capable of making a 20 or 30 meter CESA. And that has always been the point.