I burnt my lips quite badly when I was a young student pilot. It was a winters day and I had put on some lip balm since my lips were a bit chapped. I had no compunction since I had done this numerous times before with no issues whatsoever, even though some of the older hands had warned against using petroleum jelly etc with an oxygen mask.
Unfortunately for me, on this particular flight, one of the drills we were to do was a simulated smoke in the cockpit / fire drill. One of the first steps was to place the oxygen to the "100%" setting from the "Normal" setting. If you flicked the switch a little too far, it would go to "Emergency O2" which was a positive pressure breathing system.
At 18000' , so around 1/2 an ATA of ambient pressure, I selected 100% and inadvertently switched it to "Emergency" and then instantly back to 100%. This allowed a short, 1/2 second puff of O2 onto my face at a pretty low pressure, into a high volume breathing mask. I would be VERY surprised if the PPO2 even got to 1 ATA.
A few seconds later I felt a burning sensation on my lips and assumed it was the chapped part hurting. A few seconds later I began to REALLY hurt. I handed over control to the instructor, pulled my mask off at 18K (that's how much it hurt) and had the strange sensation of seeing the smoke from my lip skin puff out of the mask.
I basically beat my lips to death and then we RTB'ed. I spent a pleasant afternoon on industrial painkillers and then a less stellar week losing my mind from the pain. I was VERY lucky to get away without skin grafts. This was all from a reaaaaally thin layer of several hours old lip balm. I was really lucky. I could have died if I had been solo but instead my bandaged face was a stark warning to my comrades, many of whom stopped using the lip balm they had been using, some for years.
So to recap:
- I did something a certain way for ages, incident free, even though older wiser heads than mine advised strongly against it.
- I heard several stories and anecdotes of other people having a serious problem but rationalised that it wouldn't happen to me because I was doing things differently.
- I had an event occur, not terribly unusual or hard to happen, but on that day the random number generator came up with my name and I got hurt.
I really hope you stop at point 2.