If you need to be nitrox certified(OC) before you can dive with it(up to 40%). Why there is exception for CCR and SCR? Are you suggesting that the respective courses will deal with the issue, ie. higher than 40% and all the way to 100%(CCR)?
You do need a basic Enriched Air Certification, but you don't need Tec 40 or TDI Advanced Nitrox. Fully closed rebreathers are a very fancy adaptation of a breathing in and out of a zip-lock bag. Clearly CO2 is going to be a bit of an issue in my scenario, so we have to toss in a little soda lime in our bag.
Picture sitting on a boat breathing in and out of the bag getting ready for the dive. We quickly discover this is workable for a short period of time, but breathing from a plastic bag has a few problems long term. As we leave the surface and descend to any depth the air inside the bag almost instantly crushes leaving us nothing to breathe. The rebreather diver solves this problem by adding gas with a fancy name, diluient, a.k.a. "dil". Dil provides additional gas in the plastic bag which reinflates it making it possible to continue breathing. Dil doesn't have to be a special gas, in fact, it can simply be air, an enriched air mix, or something more exotic like Trimix/Heliox. By now you're probably wondering how we didn't pass out from a lack of oxygen?? Let's first reexamine the sources of oxygen available to the rebreather diver. For practical purposes there are three sources of oxygen, 1) oxygen expired by the diver 2) oxygen fraction in the diluient 3) oxygen cylinder.
When diving closed circuit you're operating a nitrox (trimix) mixing station on your back in real time. Instead of selecting a fraction of oxygen, i.e. I'm diving 36% and I can't go below 100ft, you're selecting a partial pressure of oxygen (a.k.a. PO2, or PPO2) for the entire duration (or majority) of a dive. Instead of planning for a peak PO2 at the very deepest (and often shortest) portion of the dive what a rebreather does is give you the ability to mix the optimized gas mixutre for every depth. If you want to raise your PO2 you can put a little shot of oxygen into the zip lock bag, if you descend and discover your PO2 climbs (from increased pressure) you can add a little shot of dil. Adding or removing oxygen and dil is essentially the same as partial pressure blending into a scuba tank which will be breathed by an Open Circuit diver. By blending oxygen and dil together we do in fact change the fraction of oxygen, i.e. we might be breathing 32% Enriched Air, but we don't care because we track oxygen against our exposure (time) and dosage (PO2). A rebreather diver simply ignores fractions placing PO2 above all else.
Consider: If you plan a single tank open circuit dive and you get a blend of Nitrox which has a 1.4 PO2 at the Max Operating Depth (MOD), you're probably only getting the maximum advantage of that gas for exactly as long as you're at the MOD for the gas. With a rebreather you're going to manage to a target PO2, a.k.a. "the set point" or "SP" and the rebreather (or rebreather diver) can mix gas constantly to maintain the optimal gas for depth. The real difference is the rebreather diver stays at the MOD for the gas at all times by using a source of 100% oxygen and dil to keep the PO2 constant.
That's basically how it works without really explaining all the nuances. As you can see, you're more of a practitioner of physics & physiology. At some point diving a rebreather you start looking at oxygen as a poison rather than a helpful drug. In effect, dosage, duration and exposure become much more interesting when you can bathe your body in it for three, four, and five hour exposures. Just sayin'
Now that we have established how a rebreather is a $10,000 zip-lock bag. Tec 40 and/or Advanced Nitrox/Deco Procedures address making short decompression dives on open circuit with a focus on planning, equipment, and execution. As you can see the basic rebreather course has topics which are far afield and may or may not even include decompression in the courses (depending on agency, rebreather type, and diver experience). You'll certainly cover nitrox adequately in any CCR class, including an in-depth review of the physics and physiology associated.