Above 40% OR partial pressure filling requires 02 cleaning. My shop has no problem with me switching back and forth between nitrox and air in the same tank. They bank their 30% nitrox, so partial pressure filling doesn't come into play.
"Gas mixes with more than 40% oxygen require equipment, including cylinder, that has been cleaned to oxygen service specifications. Because the cylinder valve and interior will be in contact with pure oxygen, if partial pressure blending with oxygen will be used, the cylinder must meet oxygen service standards, even if the final enriched air blend will have less than 40% oxygen. The standard SCUBA cylinder doesn't meet these requirements." ~PADI
"If an enriched air cylinder that has been prepared for oxygen service is accidentally filled from a conventional air source, it must be serviced and cleaned by someone qualified to service enriched air equipment before being exposed to more than 40% oxygen again." ~PADI
I've never been refused nitrox because I didn't have an 02 clean sticker. But then I've never used a dive shop that does partial pressure filling.
The definition in contention is "conventional air source". oca and hyp e is not conventional air. Yet many say if yo fill a nitrox tank with OCA you have to reclean to put nitrox in it again. that is BOGUS. Yet practiced.
Your first paragraph is correct you have to have a cylendar to qualify for the highest O2 contents it will be exposed to. Yet many see no difference between PP 30% and banked 30%. Psi admits that their 23.5% is based in the what if concept. what if you PP blended a 23.5% mix you would have pure 02 above 50psi and then top off with air if you used an empty tank to star with. the worst case scenereo point of view. You can have 23% at 3k but you cant have 23.5% greater than 50 psi with out O2 cleaning.