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@ICatchBadGuys what was said above is the real answer. Nitrox is worth it IF you hit the NDL time before you run out of gas. If you run out of gas first, then at least on that specific dive, there was no justification in diving nitrox as far as extending your dive time. There may be other fringe benefits, but that's up to you to figure out. Unfortunately without knowing the specific dive plans, your SAC rates, and which computer set to which conservatism setting, it's largely impossible to determine if there will be a direct benefit in your dive time.
In general, as I'm sure was also said above, is that it doesn't hurt to have lower inert gas loading as you go up through the week and it is highly unlikely that you won't go up against the NDL's before you hit gas limits. One potential exception to that is if you're doing mostly shore dives and if so, you basically dive until you hit NDL, then start coming up shallower and shallower "riding the ndl" until you run out of gas if you can get into areas shallower than 30ft where there are things worth looking at.
In general, as I'm sure was also said above, is that it doesn't hurt to have lower inert gas loading as you go up through the week and it is highly unlikely that you won't go up against the NDL's before you hit gas limits. One potential exception to that is if you're doing mostly shore dives and if so, you basically dive until you hit NDL, then start coming up shallower and shallower "riding the ndl" until you run out of gas if you can get into areas shallower than 30ft where there are things worth looking at.