I know a few people who've picked up tanks that hadnt gotten an air top off and were basically 100% o2.Are you sure? I don't remember the last time an incident occurred where an air diver got nitrox. Do you?
However, this just lends strength to my argument that all modern OW scuba classes should include Nitrox certification. If you can't dive air without verifying the contents your self, they you can't dive till Nitrox Certified.
The OP doesnt know ANYTHING about the gas in these tanks. Not even who filled it and if they used a paintball compressor with no filtration.