Well, rats. I know
someone who has a few MK5 NOS caps that would have solved your MK5 issues.
He could have put them in a box heading your way just a couple of days ago. But I digress. The MK9 & 10 are a different matter because the piston head seal is in the body. But before we (you) do anything radical, have you confirmed that the pits/grooves are causing a problem? A leak in that area would manifest itself by blowing bubbles out the ambient chamber. If no bubbling under pressure exist then I would live with it. If you have bubbling, then your idea of using a cylinder hone followed by fine grit emery cloth might produce acceptable results. If I remember correctly, the last time I rebuilt a hydraulic clutch slave cylinder the stones were 400 grit-so they are available. If you abrade the cylinder uniformly, piston canting should not be an issue.
I agree that Dow Corning 111 is a better choice at this point as you might be wasting expensive Christo Lube/Tribo-lube/Krytox and even so-there's nothing wrong with Dow 111 for less than 40% O2 in the first place. It might not be as "good" a lubricant in the sense that PTFE grease reduces friction better than silicone grease, but the silicone based product has better "staying" power. The PIA regs I've rebuilt that had a proper job of packing with silicone grease were pristine on the inside.
How to pack? No air pockets in the grease is the key. I start with a peg in the body where the piston hole is so I don't push grease into it. Before installing the piston and spring, start packing the chamber-guesstimate to lessen the loss of grease but don't skimp. Then, install the spring (you did remember how many shims you removed right?) and pack some more. Last, remove the peg and install the piston (remember to use a bullet) and then screw on the pre-assembled cap/turret assembly. You should get grease oozing out of the ambient ports-and more when you pressurize. Recover the lost lubricant and put it into a plastic bag for later use as an o-ring "lube-o-matic" (thanks to Vance Harlow or was it Pete Wolfinger for that tip.)
Now, forget my drivel in the above paragraph. I just remember our very own
@superstar made a MK10 packing video.
Please start with the MK 5. If successful carry on with the others. If no joy on the MK 5, don't tell anyone I said it was ok to use a (fine grit) hone and contact me so I can send a replacement cap. If successful-post pictures.
Couv