yeah so one of the things you should do from time to time is breathe off of that octo to ensure that it's working. Part of the check gear before you set it up, after you set it up, before you get in the water, after you get in the water, before you descent, after you finish descent and constantly throughout the dive. That being said, you can replace the left knob with a metal one which won't spin, and to fully turn off a post is difficult to do. Partially turn off sure, but any time you feel yourself hit the ceiling you should reach back and check that and the manifold to make sure you didn't bust it. You can get hard plastic knobs without a whole lot of grip that will be more difficult to spin off as well. Redoing the threads on the valves would be a potential solution, but that would be a problem.
Thorndikes learning laws, law of primacy. We first learn right tighty left loosey. instinct says to do that when we turn valves and having to turn them both forward or both back would be problematic. Could be done, but then you'd have to get all new manifolds, have to deal with one normal and one backwards etc etc. Not saying it's a bad idea, but it's not practical by any means and would cause more problems than the very rare roll-off. It's far simpler to get divers to say "self, i just hit the ceiling, i should probably check my left post" If you are too tasked to think about that you have no business being in a cave or diving doubles, sorry. That's just a very simple thing that no amount of task loading should cover.