Valves ... you can put DIN valves on any cylinder. I have them on all of mine ... two LP95's, two MP72's, and two E8 119's. Those tanks have a fill pressure of 2640, 3300, and 3442 respectively. So valve type really isn't an issue. Most new cylinders nowadays come with "pro" valves anyway ... with the little inserts you can use to make them either yoke or DIN.
Filling issues ... sorry, in my area I am not aware of a single shop that cannot fill an HP cylinder. There are some resorts on Van Isle that I know of ... and some charter boats with on-board filling ... that have difficulty, but those are mostly capacity issues due to the nature of the operation.
PP blending issues ... logic it through. You've got an LP cylinder and an HP cylinder. You fill each with a specific amount of O2, Then you finish filling with air. Given similar fill rates, you'll end up with a much warmer HP cylinder at the end of the fill, compared to the LP cylinder. You fill both with O2 when they're pretty cool (since the pressure's pretty low and you're doing that first), then you top with air to a much higher pressure. Since the temp was much cooler when the O2 pressure was measured than when the finished cylinder was measured, you didn't really put as much air in that cylinder as you calculated you'd need (due to heat-induced expansion) ... your calculations don't take heat expansion into consideration. Therefore your final EAN measurement will be higher than predicted. Since the HP cylinders are filled to a higher pressure than the LP cylinders, more heating occurs ... and the greater your error will be.
Of course, you can always leave your cylinders to cool off and have them topped after they've cooled ... but in reality a proper PP nitrox fill takes so long that most folks are anxious to grab their cylinders and boogie as soon as it's off the whip.
Weight of cylinders ... not sure where this becomes a wetsuit/drysuit issue, since it's the buoyancy characteristic of the cylinder, and not the weight, that determines how much lead you get to remove from your weight belt. And FWIW - of my own cylinders, the lightest (MP72's) are the most negative ... and the ones that enable me to wear the least amount of lead on my waist.
... Bob (Grateful Diver)