I've got some original silicone valves by USD from the 1990s. They did make them for the mouthpiece, but not for the diaphragm. I heard that they made some duckbills of silicone, but never saw any. The USD catelog from 1973 says that they have "new, improved non-return valves" in the mouthpiece. So I'm sure that at one point USD had introduced silicone non-returns for the mouthpiece. I'm still using mine in my Trieste II.
SeaRat
SeaRat